Shoppenhangers Road in Maidenhead was closed this morning after a Royal Mail van was involved in an accident with a blue VW Polo car just before 11.30am.
The driver of the van was taken to Wexham Park Hospital in Slough with suspected head injuries.
Firefighters, who joined ambulance staff on the scene, were still working to free the trapped woman driver of the VW an hour after the accident happened, at 12.30pm.
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The victim of an assault in Cippenham was flown to hospital by air ambulance this afternoon.
A rapid response vehicle, an ambulance officer, an air ambulance and an ambulance crew were all called to an address in Earls Lane at 2.10pm.