John Walker, 51, of Cotterells, Hemel Hempstead, will appear at Aylesbury Crown Court charged with two counts of rape.
The other relates to an alleged rape of a woman in Wembley, London, in 1987.
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The crash, which took place at about 7am today (Thursday), involved three vehicles. One man sadly died as a result of the collision and his next of kin have been informed.